Shhyamali De is known for being married to filmmaker Raj Nidimoru. Raj Nidimoru has recently been linked romantically to actress Samantha Ruth Prabhu, fueling interest in Shhyamali and her relationship with her husband.

Shhyamali De is a filmmaker herself, having worked as an assistant director in the Bollywood film Rang De Basanti. She also serves as a creative consultant for her husband, Raj Nidimoru. Raj has credited Shhyamali for her guidance on casting decisions and for keeping him grounded due to her non-film background. In an interview with Deccan Chronicle, Raj stated, "Shhyamali De, my wife, constantly advises me about casting. She comes from a non-filmy background, so she keeps us grounded always".

Raj Nidimoru and Shhyamali De reportedly married in 2015 and have a daughter. While some reports suggest they are still married but living separately, there has been no formal announcement of a divorce. Shhyamali's Instagram account still features pictures of her with Raj. The last photo she posted with Raj was on Valentine's Day 2023.

Samantha Ruth Prabhu and Raj Nidimoru have worked together on several projects, including The Family Man, Citadel: Honey Bunny, and the upcoming Rakt Brahmand: The Bloody Kingdom. They are also co-owners of the Chennai Super Champs pickleball team. Recent photos of Samantha and Raj together, including one where Samantha is resting her head on Raj's shoulder, have led to increased speculation about their relationship. Fans have noticed their close bond, with some even coining the nickname "Samraj".

Amidst the rumors, Shhyamali De shared a cryptic note on social media, which has since gone viral. The specific content of the note is not detailed, but its timing, amidst the growing speculation around Samantha and Raj, has attracted attention.